Redox Titration (Vitamin C with iodine)

Redox Titration Demo

Redox Titration

Vitamin C with Iodine

Perform a redox titration to determine the concentration of Vitamin C (ascorbic acid) in a solution using iodine. Add starch indicator and titrate until the endpoint is reached (persistent blue-black color).

Vitamin C Solution (Colorless)
1.0
Observation:

Prepare the vitamin C solution and add starch indicator. The solution will turn blue-black when all vitamin C is oxidized by iodine.

Volume Used:

Iodine solution used: 0.00 mL

Calculations:

Vitamin C concentration: 0 mg/mL

The Science Behind Redox Titration

Key Concepts:

Redox titration involves a oxidation-reduction reaction between analyte and titrant:

  • Vitamin C (Ascorbic acid): Acts as a reducing agent (gets oxidized)
  • Iodine (I₂): Acts as an oxidizing agent (gets reduced to iodide I⁻)
  • Starch indicator: Forms a blue-black complex with excess iodine
Chemical Reaction:

C₆H₈O₆ (ascorbic acid) + I₂ → C₆H₆O₆ (dehydroascorbic acid) + 2H⁺ + 2I⁻

The endpoint is reached when all ascorbic acid is oxidized and free iodine reacts with starch.

Applications:

This method is widely used to determine vitamin C content in fruits, juices, and supplements.

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