Colligative Properties (Freezing point depression)

Colligative Properties Demo

Colligative Properties

Freezing Point Depression

Observe how adding a solute to a solvent lowers its freezing point. Compare the freezing of pure solvent versus solution. Adjust the solute concentration to see how it affects the freezing point depression.

20°C
10°C
0°C
-10°C
-20°C
Temperature: 20°C
0.5
Observation:

The pure solvent will freeze at 0°C, while the solution will freeze at a lower temperature. The freezing point depression depends on solute concentration.

Freezing Points:

Pure solvent: 0°C | Solution: -0.93°C (ΔT = 0.93°C)

The Science Behind Freezing Point Depression

Key Concepts:

Colligative properties depend on the number of solute particles, not their identity:

  • Freezing point depression: Solution freezes at lower temperature than pure solvent
  • ΔT = Kf × m × i (Kf = cryoscopic constant, m = molality, i = van't Hoff factor)
  • For water: Kf = 1.86°C·kg/mol
Molecular Explanation:

Solute particles disrupt the orderly arrangement of solvent molecules needed for freezing, requiring lower temperatures to overcome this disruption and form a solid.

Applications:

Used in antifreeze for car radiators, de-icing roads with salt, and in frozen dessert preparation.

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