Verify Boyle’s/Charles’s Law

Gas Thermodynamics Lab: Boyle's and Charles's Law

Gas Thermodynamics Lab: Verification of Boyle's & Charles's Law

Physics - Std 11: Pressure, Volume, and Temperature Relationships

Investigate the fundamental gas laws: **Boyle's Law** ($PV = \text{constant}$) and **Charles's Law** ($V/T = \text{constant}$). These laws describe the behavior of ideal gases under specific constant conditions.

Key Equations & Concepts

Combined Gas Law:

$$ \frac{P_1 V_1}{T_1} = \frac{P_2 V_2}{T_2} $$ (This is the basis for all challenges, as it incorporates both Boyle's and Charles's Law).

Boyle's Law (Isothermal):

At constant $T$: $$ P_1 V_1 = P_2 V_2 $$ (Pressure is inversely proportional to Volume).

Charles's Law (Isobaric):

At constant $P$: $$ \frac{V_1}{T_1} = \frac{V_2}{T_2} $$ (Volume is directly proportional to Temperature, $T$ must be in Kelvin).

Experiment 1: Boyle's Law Verification (Isothermal Process)

Adjust the pressure applied to the piston and verify the constancy of the $PV$ product.

Applied Pressure ($P$)
2.0 $\text{atm}$
Gas Volume ($V$)
5.0 $\text{L}$
$PV$ Product
10.0 $\text{atm}\cdot\text{L}$

Volume is inversely proportional to Pressure (at $T=300 \text{ K}$).

Experiment 2: Charles's Law Challenge (Isobaric Process)

Given the initial state and final temperature, calculate the final volume ($V_2$) or the final temperature ($T_2$).

Initial Volume $V_1$
10.0 $\text{L}$
Initial Temp $T_1$
300 $\text{K}$
Final Volume $V_2$
15.0 $\text{L}$
Verify the final state using $\frac{V_1}{T_1} = \frac{V_2}{T_2}$.
Result Status
Absolute Temperature Scale:

Both Charles's Law and the Ideal Gas Law **only** work when temperature ($T$) is measured on the **absolute (Kelvin) scale**. $T_{\text{Kelvin}} = T_{\text{Celsius}} + 273.15$.

Kinetic Theory and Microscopic View

Ideal Gas Law ($PV=nRT$):

This law combines all the individual gas laws (Boyle's, Charles's, Avogadro's). It describes the macroscopic state of a system in terms of microscopic properties (molecular collisions).

Isothermal vs. Isobaric:

**Isothermal** means constant temperature (Boyle's Law). **Isobaric** means constant pressure (Charles's Law). These constraints simplify the Ideal Gas Law for analysis.

Work and Internal Energy:

In an **isobaric** process (Charles's Law), both **work** and **internal energy** change, meaning heat transfer is required to maintain constant pressure while the volume changes.

Leave a Comment

Your email address will not be published. Required fields are marked *

Scroll to Top